Parameter recovery was assessed within mixture confirmatory factor analysis across multiple estimator conditions under different simulated levels of mixture class separation. Mixture class separation was defined in the measurement model (through factor loadings) and the structural model (through factor variances). Maximum likelihood (ML) via the EM algorithm was compared to a Markov chain Monte Carlo (MCMC) estimator condition using weak priors and a condition using tight priors. Results indicated that the MCMC weak condition produced the highest bias, particularly with a weak Dirichlet prior for the mixture class proportions. Specifically, the weak Dirichlet prior affected parameter estimates under all mixture class separation conditions, even with moderate and large sample sizes. With little knowledge about parameters, ML/EM should be used over MCMC weak. However, MCMC tight produced the lowest bias under all mixture class separation conditions and should be used if tight and accurate priors can be placed on parameters. (Contains 7 tables, 2 figures, and 10 footnotes.)