In the linguistics field, liaison in French is interpreted as an indicator of interactions between the various levels of language organization. The current study examines the same issue while adopting a developmental perspective. Five experiments involving children aged two to six years provide evidence for a developmental scenario which interrelates a number of different issues: the acquisition of phonological alternations, the segmentation of new words, the long-term stabilization of the word form in the lexicon and the formation of item-based constructions. According to this scenario, children favour the presence of initial CV syllables when segmenting stored chunks of speech of the type word1-liaison-word2 ("les arbres" "the trees" is segmented as /le/+/zarbr/). They cope with the variation of the liaison in the input by memorizing multiple exemplars of the same word2 (/zarbr/, /narbr/). They learn the correct relations between the word1s and the word2 exemplars through exposure to the well-formed sequence ("un"+"/narbr/", "deux+/zarbr/). They generalize the relation between a word1 and a class of word2 exemplars beginning with a specific liaison consonant by integrating this information into an item-based schema (e.g. "un"+/nX/, "deux"+/zX/). This model is based on the idea that the segmentation of new words and the development of syntactic schemas are two aspects of the same process.