ERIC Number: EJ814868
Record Type: Journal
Publication Date: 2008-Nov
Pages: 3
Abstractor: As Provided
ISBN: N/A
ISSN: ISSN-0021-9584
EISSN: N/A
Available Date: N/A
Gas Nonideality at One Atmosphere Revealed through Speed of Sound Measurements and Heat Capacity Determinations
Halpern, Arthur M.; Liu, Allen
Journal of Chemical Education, v85 n11 p1568-1570 Nov 2008
Using an easy-to-make cylindrical resonator, students can measure the speed of sound in a gas, u, with sufficiently high precision (by locating standing-wave Lissajous patterns on an oscilloscope) to observe real gas properties at one atmosphere and 300 K. For CO[subscript 2] and SF[subscript 6], u is found to be 268.83 and 135.25 m s[superscript -1], respectively, versus their ideal-gas (zero-pressure) values of 270.15 and 136.67 m s[superscript -1]. These differences arise from intermolecular interactions. It is shown that if the molar isobaric heat capacities, C[subscript p], m, are calculated from the one atmosphere u values assuming perfect gas behavior, significant errors are produced. For CO[subscript 2] and SF[subscript 6] these errors are 2.7% and 25%, respectively. Experimental C[subscript p], m values are compared with those obtained based on the equipartition theorem. (Contains 1 figure and 2 tables.)
Descriptors: Molecular Structure, Measurement Techniques, Science Experiments, Laboratory Experiments, Computation, Chemistry, College Science, Science Instruction, Acoustics, Scientific Concepts
Division of Chemical Education of the American Chemical Society. Subscription Department, P.O. Box 1267, Bellmawr, NJ 08099-1267. Tel: 800-691-9846; Tel: 856-931-5825; Fax: 856-931-4115; e-mail: jchemed@egpp.com; Web site: http://www.jce.divched.org
Publication Type: Journal Articles; Reports - Evaluative
Education Level: Higher Education
Audience: N/A
Language: English
Sponsor: N/A
Authoring Institution: N/A
Grant or Contract Numbers: N/A
Author Affiliations: N/A