The relationships among emotional intelligence, social coping, and psychological distress were investigated in a sample of 624 Chinese gifted students in Hong Kong. A mediation-effect model specifying that emotional intelligence had an effect on psychological distress mediated by social coping was hypothesized and tested using structural equation modeling procedures. For comparison, a direct-effect model and a direct-and-mediation-effect model were also fitted to the data. The results indicated that the mediation-effect model provided an adequate and good fit, suggesting that the effects of self-relevant and other-relevant emotional intelligence on psychological distress were mediated by avoidant coping and social-interaction coping, respectively. Implications of the findings for enhancing emotional intelligence of students and in promoting the use of adaptive social coping strategies for their psychological well-being are discussed. (Contains 6 tables and 1 figure.)