Affect and habitus are used in the paper to harness the intermingling of race and class in the young people's everyday identity practices at school, as they aspire to embody 'Black excellence'. This paper draws on ethnographic data collected with working-class Black-British young people aged between 16 and 18. Through the careful management of identity and reputation, the young people in this paper negotiate affective struggles to attain and secure a high academic status within a deeply neoliberalised school context. The paper argues that the identity discourse of 'Black excellence' connects dimensions of class and race in the young people's identity work. Black excellence is described as classed and racialised reflexivity which helped the young people pivot their identity as they sought to maximise their educational opportunities to transition into elite universities.