In educational reform, people actively promote educational innovation by applying intelligent technology. As the main participants in education, people experience a series of psychological and cognitive changes in the teaching process. This autonomy and uncertainty will directly affect the effect of network teaching. Due to the variability in the characteristics of individuals, following the psychological perception and subjective value of people and optimizing the development of wisdom education with a reasonable technical cognitive attitude have become a focus. This study uses the grounded theory method to conduct in-depth interviews and questionnaire surveys on 330 e-learners and extracts 400 codes, 38 concepts, 9 categories and 4 core categories. This paper reconstructs the theoretical model of psychological distance in the network education process and identifies four new dimensions: cost distance, initiative distance, control distance and interaction distance. In addition, the four dimensions reflect four core value needs of learners for online education: convenience, self-efficacy, self-identity and binding force. The paper provides a good theoretical basis to improve the user experience and satisfaction in online education and optimize the level of intelligent education.