The purpose of this study is to explore whether training job seekers in the positive psychological resource of psychological capital (PsyCap) facilitates their job search activities and outcomes. Adopting a quasi-experimental design, we examined the impact of the PsyCap training on job seekers success. Our findings demonstrated that those who received the PsyCap training (treatment group) demonstrated higher levels of job search behavior and obtained employment at a higher rate, 3 months following the intervention, compared to the control group. The important role of PsyCap in pursuing employment as well as the practical implications of developing the positive psychological resource of PsyCap are discussed.