This study examined the factorial structure of the Polish version of the Parental Burnout Assessment (PBA-PL) and its relation with other variables, previously shown to be antecedents or outcomes of parental burnout. The PBA-PL was administered to a total sample of 2,130 parents along with other instruments depending on the study. Factorial analyses of the PBA-PL supported both the original four-factor model of parental burnout (exhaustion related to parenting, feelings of being fed up with parenting, emotional distancing from one's children, and contrast with previous parental self) and a second-order model with a global parental burnout underlying the four first-order factors. Both subscale and global scores were reliable. Significant correlations were found between PBA-PL and neuroticism, emotional intelligence, maladaptive perfectionism, perceived social support, depressive symptoms, marital satisfaction, and life satisfaction. PBA-PL also predicted both parental neglect and parental violence beyond socio-demographic factors, depression, and job burnout.