ERIC Number: EJ1215771
Record Type: Journal
Publication Date: 2019-May
Pages: 5
Abstractor: As Provided
ISBN: N/A
ISSN: ISSN-0021-9584
EISSN: N/A
Available Date: N/A
Overdriven Pulsed Light Emitting Diodes: An Inexpensive Excitation Source for Time-Resolved Luminescence Lifetime Measurements
Drew, Steven M.; Gross, Deborah S.; Hollingsworth, William E.; Baraniak, Thomas; Zall, Christopher M.; Mann, Kent R.
Journal of Chemical Education, v96 n5 p1046-1050 May 2019
Time-resolved luminescence lifetime measurements are an important photophysical technique. However, access to this technique at the undergraduate level is limited by the expense of the instrumentation needed to create the well-defined light pulses required to measure the luminescence decay of an excited state molecule. We present here an inexpensive, improved light emitting diode (LED) circuit that is capable of supplying bright light pulses. Our circuit is designed to overdrive the LED resulting in a bright excitation light source with a well-defined square wave pulse shape. This allows for the facile measurement of luminescent molecules with decay lifetimes in the hundreds of nanoseconds to microsecond range. Data are presented for five UV, violet, and blue LEDs as driven by the improved circuit that can be used as a guide for selecting the best excitation light source for a particular molecule of interest. Our students have studied the quenching of aqueous tris(bipyridine)ruthenium(II) chloride with ferric ion using an overdriven blue LED as an excitation source. While ferric ion is not an efficient quencher compared to molecular oxygen, it is much easier to handle, allowing for the preparation of accurate standard solutions free of dissolved oxygen.
Descriptors: Chemistry, Science Instruction, Lighting, Undergraduate Study, College Science, Scientific Concepts, Light, Molecular Structure, Science Laboratories, Laboratory Equipment
Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Descriptive
Education Level: Higher Education; Postsecondary Education
Audience: N/A
Language: English
Sponsor: N/A
Authoring Institution: N/A
Grant or Contract Numbers: N/A
Author Affiliations: N/A