As ecological globalization intensifies, rural waste recycling and management has become a global concern. China's proactive efforts are significant for revitalizing domestic rural ecosystems, offering valuable insights into global environmental governance. The rampant dumping and informal processing of hazardous waste in rural China pose severe threats to local ecological balance and public safety. Thus, efficiently recycling hazardous rural and agricultural waste is pivotal for China's rural ecological and environmental governance. This study adopts a participatory governance perspective and establishes a theoretical framework for dual principal-agent relationships. This framework examined 22 cases of rural governance spanning Eastern, Central, and Western China. This study evaluated governance mechanisms in four dimensions: policy, material, human, and social capital, using the fuzzy-set qualitative comparative analysis method. The key findings include: (1) The adverse orientation and behavior of hazardous waste recycling governance in rural areas stem from the combined impacts of multiple complex factors. (2) The synergistic interplay between policy, human, and social capital is crucial for advancing hazardous waste recycling governance in rural settings. (3) Three pathway mechanisms--socially driven, market-oriented, and system participation--facilitate the effective governance of hazardous waste recycling. Innovative practices in hazardous waste recycling and management within rural China yielded positive domestic impacts and profoundly influenced global environmental governance. China's experiences and approaches motivate other nations and regions, showcasing responsibility and dedication to international environmental governance and bolstering Chinese contributions to creating a cleaner, beautiful world.