The enantioselective synthesis of drugs is of fundamental importance in the pharmaceutical industry. In this experiment, students synthesize either enantiomer of warfarin, a widely used anticoagulant, in a single step from inexpensive starting materials. Stereoselectivity is induced by a commercial organocatalyst, ("R","R")- or…

This experiment investigates the methylation of 2-naphthol with dimethyl carbonate. The volatility of the substrates, products, and co-products allows the reaction to be performed using a continuous-flow gas-phase setup at ambient pressure. The reaction uses catalytic quantities of base, achieves high conversion, produces little waste, and…

In "JCE" Activity #67, "Flame Tests: Which Ion Causes the Color?", Michael Sanger describes how to conduct flame tests with household items. We have used this activity in outreach settings, and have extended it in a variety of ways. For example, we have demonstrated large-scale strontium (red), copper (green), and carbon (blue) flames using only…

There is a standard convention that the icosahedral groups are classified separately from the cubic groups, but these two symmetry types have been conflated as "cubic" in some chemistry textbooks. In this note, the connection between cubic and icosahedral symmetries is examined, using a simple pictorial model. It is shown that octahedral and…

The colour of the copper layer deposited on a graphite electrode during electrolysis of an aqueous solution of copper(II) sulfate looks whitish-grey when inspected in situ. Taking the electrode out of the solution reveals the familiar orange-red colour of deposited copper. The explanation is found in terms of the almost ideal complementary colours…

We present a physically interesting toy, which is easily constructed and operated--the so-called buzzer. In spite of its simplicity, its physical analysis turns out to be rather complex. Thus, it comes as no surprise that most of its users are not familiar with the underlying physical mechanism. In this paper we propose a physical model which…

An analytic approximation of the solution to the differential equation describing the oscillations of a simple pendulum at large angles and with initial velocity is discussed. In the derivation, a sinusoidal approximation has been applied, and an analytic formula for the large-angle period of the simple pendulum is obtained, which also includes…

In his essay on the role of creativity in science and of science in society, Hisham B. Ghassib (2010) points out that science is much more a series of common attitudes and practices rather than a clearly delineated set of methods. The author agrees. The author also agrees that scientific knowledge is playing a key role in the forward development…

Unlike many other topics in basic physics, series and parallel resistances are rarely noticed in the real life of an ordinary individual, making it difficult to design a laboratory activity that can simulate something familiar. The activities described here entail minimal costs and are based on a puzzle-like game of tracking wire connections. A…

Most introductory physics students have seen vehicles with nonstandard wheel diameters; some may themselves drive "low-rider" cars or "big-wheel" pickup trucks. But how does changing wheel diameter affect speedometer readout for a given speed? Deriving the answer can be followed readily by students who have been introduced to rotation, and it…

A forgotten experiment by Andre Blondel (1914) proves, as held on the basis of theoretical arguments in a previous paper, that the time variation of the magnetic flux is not the cause of the induced emf; the physical agent is instead the vector potential through the term [equation omitted] (when the induced circuit is at rest). The "good…

Dimensional analysis is a simple, clear and intuitive method for determining the functional dependence of physical quantities that are of importance to a certain process. However, in physics textbooks, very little space is usually given to this approach and it is often presented only as a diagnostic tool used to determine the validity of…

This article describes a lesson where students explore the absorbency of several towels with different weaves and weights. The lesson follows the 5E learning-cycle model and incorporates engineering in the sense of product testing with a focus on the relationship between the weave of a towel and its absorbency. The National Science Education…

Making connections is one of the most important foundations involved in learning mathematics. Two projects are presented in this article: one involving Newton's Second Law of Motion and the other involving the determination of star numbers, a type of figurate number. The two invoke seemingly different modalities for students at different levels of…

The main objective of this experiment is to determine the amount of nicotine in commercial brand cigarettes by means of a nonaqueous acid-base titration. A simple glass device simulating a smoker is proposed, which allows the determination of the volatilized, filter retained, and inhaled portions. Students will readily see that the amount of…