ERIC Number: EJ1442199
Record Type: Journal
Publication Date: 2022-Sep
Pages: 9
Abstractor: As Provided
ISBN: N/A
ISSN: ISSN-0021-9584
EISSN: EISSN-1938-1328
Available Date: N/A
Exploring Resonance Raman Scattering with 4-Nitrophenol
Catherine L. Jahncke; Wenyao Zhang; Bethany M. DeMuynck; Adam D. Hill
Journal of Chemical Education, v99 n9 p3233-3241 2022
Raman scattering is a powerful tool for revealing the vibrations of molecules, but as a nonlinear optical phenomenon, its signals can change via mechanisms like resonance enhancement that have no direct analogue in infrared spectroscopy. In this work, complementary measurements conducted on 4-nitrophenol and its conjugate base allow students to directly control the variables responsible for enhancement. Changing sample UV-vis absorbance with pH and excitation color with the addition of a diode laser allows students to explore the criteria for resonance Raman scattering: only the conjugate base and 405 nm laser in combination produce enhancement. Adjustments to the experiment make it suitable for either an upper-level undergraduate course labor an independent inquiry project.
Descriptors: Science Instruction, Chemistry, Science Laboratories, Lasers, Undergraduate Study, College Science, Color, Scientific Concepts, Science Experiments
Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Research
Education Level: Higher Education; Postsecondary Education
Audience: N/A
Language: English
Sponsor: N/A
Authoring Institution: N/A
Grant or Contract Numbers: N/A
Author Affiliations: N/A