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ERIC Number: EJ1442199
Record Type: Journal
Publication Date: 2022-Sep
Pages: 9
Abstractor: As Provided
ISBN: N/A
ISSN: ISSN-0021-9584
EISSN: EISSN-1938-1328
Available Date: N/A
Exploring Resonance Raman Scattering with 4-Nitrophenol
Catherine L. Jahncke; Wenyao Zhang; Bethany M. DeMuynck; Adam D. Hill
Journal of Chemical Education, v99 n9 p3233-3241 2022
Raman scattering is a powerful tool for revealing the vibrations of molecules, but as a nonlinear optical phenomenon, its signals can change via mechanisms like resonance enhancement that have no direct analogue in infrared spectroscopy. In this work, complementary measurements conducted on 4-nitrophenol and its conjugate base allow students to directly control the variables responsible for enhancement. Changing sample UV-vis absorbance with pH and excitation color with the addition of a diode laser allows students to explore the criteria for resonance Raman scattering: only the conjugate base and 405 nm laser in combination produce enhancement. Adjustments to the experiment make it suitable for either an upper-level undergraduate course labor an independent inquiry project.
Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Research
Education Level: Higher Education; Postsecondary Education
Audience: N/A
Language: English
Sponsor: N/A
Authoring Institution: N/A
Grant or Contract Numbers: N/A
Author Affiliations: N/A