The rate of the sonochemiluminescence reaction of luminol in alkaline medium can be increased in the presence of carbon tetrachloride, chloroform, and bromoform. The presence of the latter activators enhances the light emission, to allow studying the kinetics of this reaction in a 4-h laboratory session using a mobile phone camera as a detector…

Millions of people do not have access to clean drinking water; thus, cost-efficient water treatment systems are vital. Chemists, environmentalists, technicians, and engineers will be the professionals making breakthroughs in this industry. This laboratory experiment aims to introduce undergraduate students to the removal of pollutants from water…

In this guided inquiry experiment, students extract catecholase enzyme from apples to catalyze the oxidation of catechol. They follow the reaction using the UV--vis absorbance of the "p"-benzophenone produced to determine the Michaelis-Menten kinetic parameters. Students make selected experimental choices within a structured framework…

Cosmetic chemistry is a prevalent part of everyday life, but there are very few undergraduate laboratories that explore this topic. Here, we present a laboratory exercise in which students use fizzing bath tablets (better known as "bath bombs") to learn about introductory kinetics. Students created their own bath bombs by combining…

Oxygen reduction reaction (ORR),as a multielectron electrode reaction, is an important electrochemical reaction in the field of electrochemical energy storage systems. Herein, a new advanced electrochemical laboratory experiment is designed for undergraduates to master the preparation of oxygen reduction catalytic electrode. Students can use…

This article describes an experiment that can be done in the classroom in a simple way, with the support of a "homemade" device or as a laboratory practice with the support of PASCO equipment. Through a theory-practice sequence, kinematic and dynamic equations were checked with qualitative and quantitative analysis, emphasizing the…

Adsorption of methylene blue and malachite green was carried out using "Luffa cylindrica" sponges as adsorbing material. We provide a very illustrative exercise about the use of common natural materials requiring little preparation to solve environmental tasks in a routine laboratory situation such as using dyes. In addition, the…

A versatile and portable apparatus was developed to demonstrate exciting visual displays of catalytic phenomena that introduce basic concepts in catalysis, renewable energy, and chemical safety, in order to pique scientific curiosity in a variety of audiences including middle and high school students, undergraduate and graduate students, and the…

In 1972 Christian B. Anfinsen received the Nobel Prize in Chemistry for "…his work on ribonuclease, especially concerning the connection between the amino acid sequence and the biologically active conformation." The understanding of this principle is crucial for physical biochemistry students, since protein folding studies, bio-computing…

In selecting from a repertoire of traditional kinetics experiments, an instructor often has to choose among having students gain experience with the graphical method, the method of initial rates, or a temperature-dependent experiment in which students construct an Arrhenius plot. This paper presents an environmentally friendly bleaching reaction…

Students in the undergraduate "transport phenomena" courses typically have a greater difficulty in understanding the theoretical concepts underlying the mass transport phenomena as compared to the concepts of momentum and energy transport. An experiment based on dissolution of carbon dioxide in water was added to the course syllabus to…

Several studies have showed the subsistence, even in students enrolled in scientific degree courses, of spontaneous ideas regarding the motion of bodies that conflict with Newton's laws. One of the causes is related to the intuitive preconceptions that students have about the role of friction as a force. In fact, in real world novices do not…

The solvent influence on the absorption spectra and the kinetics of the back reaction of the 1',3'-dihydro-1',3',3'-trimethyl-6-nitrospiro(2H-1-benzopyran-2,2'-2H-indole) (6-NO2-BIPS) has been investigated by means of temperature-controlled, UV-visible spectroscopic measurements. The back reaction process was proved to follow first-order kinetics…

Undergraduate students in the teaching laboratory have successfully used N-heterocyclic carbenes (NHCs) as organocatalysts for the acetylation of primary alcohols, despite the high water sensitivity of uncomplexed ("free") NHCs. The free NHC readily reacted with chloroform, resulting in an air- and moisture-stable adduct that liberates…

A "one-pot" method for acquiring kinetic data for the reactions of a series of substituted aromatic esters with potassium hydroxide using [supserscript 13]C NMR spectroscopy is described, which provides an efficient way to obtain sufficient data to demonstrate the Hammett equation in undergraduate laboratories. The method is…