Energy conversion devices such as fuel cells, metal-air batteries, and electrolyzers have been envisaged as possible solutions for cutting down the continuous accumulation of greenhouse gases resulting from the combustion of fossil fuel. The bottleneck reaction for these devices is the oxygen reduction reaction (ORR) occurring at the cathode. The…

The following activity was developed to allow students to actively participate in and measure the kinetics of a multistep process. Each group of students is given a stack of blank coloring pages, each with a rainbow design printed on it. Each student in a group is given a different color crayon and colors in their portion of the picture before…

Friction is one of the most important forces studied in classical mechanics, and still is the subject of pedagogical literature. In a small series of problems stated below, we consider a particle sliding down a curve under the actions of gravity and kinetic friction. Unlike many of the referenced sources, we neglect the centripetal force arising…

"k[subscript cat]/K[subscript M]" is a fundamental kinetic parameter as important as "k[subscript cat]" in enzyme kinetics. Although the parameter provides critical information on how the enzyme lowers the energy barriers along the reaction pathway for catalysis, "k[subscript cat]/K[subscript M]" is frequently…

Teaching special relativity to lower-division students is challenging because results such as time dilation, length contraction, and frame dependence of simultaneity are counterintuitive. The literature is extensive, so only a brief list is given here, with articles divided roughly between discussions of general principles and calculations applied…

A loop-the-loop experiment usually involves a ball rolling around a vertical loop. A different version of the experiment is described where a nut was allowed to slide around a vertical loop. In both experiments there is a large decrease in kinetic energy when the ball or the nut first enters the loop.

Theoretical and practical foundations of basic electrochemical concepts of heterogeneous charge transfer reactions that underline electrochemical processes are presented for their detailed study by undergraduate and postgraduate students. Several simple methods for calculating key variables, such as the half-wave potential, limiting current, and…

In order to describe the velocity of two bodies after they collide, Newton developed a phenomenological equation known as 'Newton's experimental law' (NEL). In this way, he was able to practically bypass the complication involving the details of the force that occurs during the collision of the two bodies. Today, we use NEL together with momentum…

Theoretical yield and extent of reaction (degree of completion) are important concepts in stoichiometry and in chemical kinetics. We provide expressions describing theoretical yield (Y) and maximum extent of reaction (fractional yield, f[subscript max]) for five examples of commonly encountered reversible chemical reactions: A [equilibrium sign]…

The problem of a disc or cylinder initially rolling with slipping on a surface and subsequently transitioning to rolling without slipping is often cited in textbooks. Students struggle to qualitatively understand the difference between kinetic and static frictional forces--i.e., whereas the magnitude of the former is known, that of the latter can…

The pharmaceutical and medicine manufacturing industry has become the largest industrial sector for the employment of chemists, indicating a need for experiments with a pharmaceutical sciences context in the undergraduate chemistry curriculum. In the pharmaceutical industry, testing drug dissolution is a key analytical task for solid oral dosage…

Alpha-particle sources are widely used in industrial and medical applications. Such applications include smoke detectors, static charge eliminators, and radiation therapy. This paper is concerned with the detection of alpha particles. A number of techniques are known for the detection of alpha particles. Those techniques include the Geiger-Müller…

Nonlinear chemical reactions produce interesting chemohydrodynamic patterns in an unstirred medium, which act as interesting demonstrations to display the novel phenomena in a nonequilibrium chemical system. Here, we report new outreach experiments: pH chemohydrodynamic patterns modulated by sodium polyacrylate in the bromate-sulfite-ferrocyanide…

The inhibition of porcine pancreatic lipase by the drug orlistat was studied through a series of activities that combine experimental and computational procedures. The enzymatic activity of the lipase was determined by measuring enzyme kinetics and calculating parameters such as K[subscript m] and V[subscript max] from experimental data. Assays of…

The distinction between pressure in a liquid and in a gas is often treated in a cursory way, or not treated at all, even in university level textbooks. Most texts fail to point out the relation between pressure and density in a gas as compared to pressure in a--virtually incompressible--liquid. In many instances this also results in a dismissive…