Presents entropy analysis of four processes: a chemical reaction, a heat engine, the dissolution of a solid, and osmosis. Discusses entropy, the second law of thermodynamics, and the Gibbs free energy function. (MVL)

The chemical and instrumental methods used in the study of transition-metal complexes provide a complete determination of their structure, bonding, and properties. It unites concepts of analytical, inorganic, and physical chemistry in a way that students might appreciate that these areas of chemistry are not different.

Discusses ways that chemists have traditionally used models to represent chemical structures. Suggests new ways to construct three-dimensional models of receptor sites using thermoplastics or heavy aluminum foil. Provides sketches and photographs of several models. Points out the advantages of using such models over traditional two-dimensional…

Topics covered in this review of analytical methods include: additives, adulteration, contamination, decomposition, carbohydrates, color, enzymes, fats, oils, fatty acids, flavor, identifying compounds, inorganic methods, moisture, organic acids, nitrogen processes, and vitamins. (MVL)

This review is devoted to methods for the determination of residues of pesticides and some related industrial chemicals. Topics include: residue methods, sampling, chromatography, organochlorine pesticides, organophosphorus pesticides, carbamate insecticides, herbicides, fungicides, pyrethrins, fumigants, and related chemicals. (MVL)

This review is divided into these topics: alkaloids, antibiotics, inorganics, nitrogen and oxygen containing compounds, steroids, sulfur containing compounds, vitamins, techniques, and miscellaneous methods. The review covers from November 1986, to October 1988. (MVL)

This review covers methods for identification, characterization, and determination of rubber and materials in rubber. Topics include: general information, nuclear magnetic resonance spectroscopy, infrared spectroscopy, thermal methods, gel permeation chromatography, size exclusion chromatography, analysis related to safety and health, and…

Describes several experiments using the techniques of thermal analysis and thermometric titrimetry. Defines thermal analysis and several recent branches of the technique. Notes most of the experiments use simple equipment and standard laboratory techniques. (MVL)

Discusses a new method for determining the eigenvalues of the Schroedinger equation when the potential energy function does not have a simple form. Describes the mathematical methods and provides an application. Lists limitations to the method. (MVL)

Questions the use of the Reactivity Selectivity Principle (RSP) by teachers and authors of texts in discussing organic reaction mechanisms. Provides some applications and failures of the use of the RSP, reviews some quantitative aspects of the RSP, and discusses some of the rationalization of the RSP failures. (TW)

Reviews techniques for the characterization and analysis of synthetic polymers, copolymers, and blends. Includes techniques for structure determination, separation, and quantitation of additives and residual monomers; determination of molecular weight; and the study of thermal properties including degradation mechanisms. (MVL)

Explores the applicability of Mulliken's united atom model to a variety of chemical systems and demonstrates its value as a teaching tool. Considers applications to first row hydrides, compounds of the first and second periods, heavy atoms, and cluster systems. (MVL)

Investigates the four week chemistry program in a summer program in science and mathematics. Identifies weekly topics for the program: (1) color and visible spectroscopy; (2) UV spectroscopy, fluorescence, and chemiluminescence; (3) IR and NMR spectroscopy; and (4) lists 12 individual projects. (MVL)

Addresses the requirements of high school students and noncrystallographers in lectures on crystals, diffraction, and structure analysis. Discusses basic understanding and a sequence that addresses these requirements. Suggests visual and descriptive teaching methods used in this effort. (CW)

Describes an experiment in which stretching a rubber band can be used to compare the statistical theory of rubber elasticity with its continuum mechanics counterpart. Employs the use of the equation of the state of rubber elasticity and the Mooney-Rivlin equation. (TW)