Keto-enol tautomerization is paramount to understanding the mechanisms involved in many organic reactions and biochemical transformations. Isomerization of an enol to a carbonyl compound is typically introduced during the discussion of the acid-catalyzed electrophilic addition of water to alkynes. The tautomerization of carbonyl compounds to enol…

Ion transport, involving the diffusion and migration of ions within the electrolyte, stands as a fundamental concept in electrochemistry and serves as the driving force for electrochemical reactions. Electric double layers are critical in the fields of electrochemical energy storage and chemical conversion, constituting a central focus of…

It is difficult for an instructor to just make up valid numbers for B[subscript x], B[subscript y], B[subscript z], E[subscript x], E[subscript y], and E[subscript z] in the creation of homework problems and test questions calculating the Poynting vector. In this paper, 25 examples are given of the electric and magnetic fields of electromagnetic…

Electricity and magnetism are closely related phenomena with a well-known symmetry found in Maxwell equations. An essential part of any electricity and magnetism course includes the analysis of different field source distributions through Gauss's and Ampere's laws to compute and interpret different physical quantities, such as electric flux,…

In this article we show that the electrostatic field intensity of a uniformly charged straight line equals that of the corresponding arc of a circle charged with the same linear density. This new method greatly simplifies the calculation of the electrostatic field of a system consisting of uniformly charged straight lines.

Theoretical and practical foundations of basic electrochemical concepts of heterogeneous charge transfer reactions that underline electrochemical processes are presented for their detailed study by undergraduate and postgraduate students. Several simple methods for calculating key variables, such as the half-wave potential, limiting current, and…

As simple and ubiquitous redox-active organic molecules, quinones participate in diverse electron transfer processes in chemistry and biological systems for energy transformation and signal transduction. We introduce here a practical exercise to study the redox potentials of benzoquinone and its two derivatives by combining the electrochemistry…

Over the past half century, computational chemistry has evolved from a niche field to a ubiquitous pillar of modern chemical research. Driven by the increased demand for computational chemistry in research settings, the undergraduate curriculum has evolved alongside to ensure that students are well-equipped for modern research. Toward this end,…

There have been a few methods described in this journal and elsewhere for measuring the wavelength of the standing electromagnetic waves in a microwave oven. Typically, these involve melting chocolate, cheese, or some other substance on a plate that is prevented from rotating. In this article I describe a more dynamic and colorful technique that…

An undergraduate-level Computational Chemistry project was incorporated initially into a Physical Chemistry course and then into the laboratory curriculum in the subsequent application. Before the introduction of the project, the lectures covered quantum chemistry, spectroscopy, and kinetics while simultaneously including computational chemistry…

In quantum mechanics courses, students are often asked to solve bound and scattering state problems. The use of an ordinary differential equation is a standard technique to solve these questions. Here, we investigated students' problem-solving processes for two typical problems of a single particle in one spatial dimension: a bound state problem…

It can readily be demonstrated that when a low frequency alternating voltage is applied to an iron-core coil the impedance is much higher than the direct current resistance of the coil. To understand how the high level of impedance arises it is necessary to explain how magnetic and electrical induction give rise to a current in the coil that…

A fairly recent paper resolves a large discrepancy in the internal energy utilized to fire a cannon as calculated by two inertial observers. Earth and its small reaction velocity must be considered in the system so that the change in kinetic energy is calculated correctly. This paper uses a car in a similar scenario, but considers the work done by…

Although for most of the time the Large Hadron Collider (LHC) at CERN collides protons, for around one month every year lead ions are collided, to expand the diversity of the LHC research programme. Furthermore, in an effort not originally foreseen, proton-lead collisions are also taking place, with results of high interest to the physics…

We look at the problem of the minimum speed of projectiles in a constant gravitational field. In the absence of resistance, the problem may be studied in the frame of a high school curriculum. One needs only Newton's laws and a minimum amount of analytic geometry to compute the orbit, which turns out to be parabolic. Furthermore, in case the…