Describes an experiment to examine the kinetics of carbamate decomposition and the effect of buffer catalysis on the reaction. Includes background information, laboratory procedures, evaluation of data, and teaching suggestions. (Author/JN)

Contains short descriptions of computer programs or hardware that simulate laboratory instruments or results of kinetics experiments, including ones that include experiment error, numerical simulation, first-order kinetic mechanisms, a game for decisionmaking, and simulated mass spectrophotometers. (CS)

Procedures for two demonstrations are provided. The solubility of ammonia gas in water is demonstrated by introducing water into a closed can filled with the gas, collapsing the can. The second demonstration relates scale of standard reduction potentials to observed behavior of metals in reactions with hydrogen to produce hydrogen gas. (Author/JN)

An advanced undergraduate laboratory experiment in inelastic electron tunneling spectroscopy is described. Tunnel junctions were fabricated, the tunneling spectra of several molecules absorbed on the surface of aluminum oxide measured, and mode assignments made for several of the prominent peaks in spectra using results obtained from optical…

Describes kinetics experiments completed in a single two-hour laboratory period at 25 degrees Centigrade of nitrito to nitro rearrangement, based on the recently discovered base-catalysis path. Includes information on synthesis and characterization of linkage isomers, spectrophotometric techniques, and experimental procedures. (SK)

Describes a laboratory scale reactor that determines the kinetics of a gas-solid catalytic reaction. The external recycle reactor construction is detailed with accompanying diagrams. Experimental details, application of the reactor to CO oxidation kinetics, interphase gradients, and intraphase gradients are discussed. (CS)

Provides a list of the reactions commonly used for introductory kinetics studies. These reactions illustrate the kinetics concepts of rate law, rate constant, and reaction order. Describes a kinetic study of the hydrolysis of 3-bromo-3-phenylpropanoic acid which offers many educational advantages. (CS)

Describes an organic chemistry experiment for teaching the basic concepts of chemical kinetics. Provides background information about first- and second-order reactions, experimental procedures of the Diels-Alder reaction between cyclopentadiene and dimethyl fumarate, and the experimental results. (YP)

Uses the context of sports surfaces to discuss the qualities of a surface that will produce a shock-absorbing effect. Discusses experiments to measure the shock-absorbing properties from two theoretical perspectives. Describes necessary equipment for the experiments. (MDH)

Reports on a technique for illustrating the dependence of the rate of reaction on the concentration of the reactants and for determining the order of reaction with respect to each reactant, the overall order of reaction, the reaction rate constant, and the half-life. (WRM)

The use of participatory lecture demonstrations in the classroom is described. Examples are given for the following topics: chromatography, chemical kinetics, balancing equations, the gas laws, kinetic molecular theory, Henry's law of gas solubility, electronic energy levels in atoms, and translational, vibrational, and rotational energies of…

This manometer is a modification of a design reported previously. It contains simplifications in the design of the manometer itself and in the associated electrical circuit. The apparatus is useful in the study of gas-phase reaction kinetics. (BB)

Outlines a simple method which shows the relation between work done in accelerating a mass and the resulting velocity of the mass. Equipment used includes a rubber ball, ramp of lumber, graph-chart, stopwatch, and hand calculator. (DH)

Describes the procedures and equipment for an experiment on the adiabatic expansion of gases suitable for demonstration and discussion in the physical chemical laboratory. The expansion produced shows how the process can change temperature and still return to a different location on an isotherm. (JN)

Clarifies misunderstanding of Millikan's experiment measuring charge on electrons. Most books describing the experiment indicate ionization of air in the apparatus caused liberation of electrons, and that these electrons were picked up by oil droplets. However, in Millikan's discussion, it is stated clearly that ions were attached to oil droplets.…