This communication describes an activity where upper-level chemistry students explore the determinability of rate constant values without concentration dependences (k[subscript true]) related to a solvent-ligand exchange in a transition metal carbonyl complex. By performing a series of multivariable linear regression (MVLR) analyses of…

In this laboratory experiment, students explore the aquatic photochemical fate of ranitidine and cimetidine, two common pharmaceutical pollutants found in wastewater. It provides an engaging environmental context for students to develop knowledge of reaction kinetics and photochemistry as well as skill in using analytical instrumentation. This…

In this communication, a remote experimental activity in chemical kinetics is described, taking into account the quantification based on the optical sensor of a smartphone. The objective pursued herein is to equip students with the appropriate tools and strategies required to empirically determine the parameters of the rate law including reaction…

Thomas Graham discovered the law that bears his name while studying gas diffusion into air and other gases. He also found that the same relationship held with gas effusion, the movement of gases through a pinhole into a vacuum. Modern understanding of diffusion and effusion is based on kinetic-molecular theory, and it is generally accepted that…

This activity introduces droplet-based millifluidics and the usage of aqueous droplets as independent chemical microreactors for reaction-kinetics studies. Students build their own droplet generators from common macroscopic glassware and connecting parts to create trains of millimeter-sized droplets in which a redox reaction takes place. The…

One of the unique advantages of electrochemistry is that the relationship between thermodynamics and kinetics is quantitative, which is the basis of voltammetry. Mathematical models of electrochemical systems take advantage of this relationship to predict the effect of changing a system property (e.g., concentration, scan rate, or rate constant)…

A 4-week mini-project is proposed for an experimental Physical Chemistry course applied in Food Science training. Activities include preparation of beet extract for the extraction of betanins and analysis of the kinetics of betanins in thermal degradation at three temperatures (60, 70, and 80 ºC). In addition to developing common laboratory…

A versatile and portable apparatus was developed to demonstrate exciting visual displays of catalytic phenomena that introduce basic concepts in catalysis, renewable energy, and chemical safety, in order to pique scientific curiosity in a variety of audiences including middle and high school students, undergraduate and graduate students, and the…

The oxidation of iron is an important reaction due to its high economic impact. In this laboratory exploration, the total order of this reaction was determined using commercially available handwarmer packets that rely on the iron-oxygen reaction to generate heat. The active ingredient in the handwarmer packet is iron, which interacts with…

Kinetics is an important part of undergraduate environmental chemistry curricula and relevant laboratory exercises are helpful in assisting students to grasp concepts. Such exercises are also useful in general chemistry courses because students can see relevance to real-world issues. The laboratory exercise described here involves determination of…

In this exercise, an actual chemical reaction, oxidation of iron in air, is studied along with a related analogue simulation of that reaction. The rusting of steel wool is carried out as a class effort. The parallel simulation is performed by students working in small groups. The analogue for the reacting gas is a countable set of discrete marble…

The importance of kinetic metastability is illustrated in detail using several common household products and recommendations are made for how this important and widespread, but often neglected, phenomenon can be more effectively presented in the introductory chemistry textbook.

First-order kinetic decay rates can be obtained by measuring the time-dependent reflection spectra of ultraviolet-sensitive objects as they returned from their excited, colored state back to the ground, colorless state. In this paper, a procedure is described which provides an innovative and unique twist on standard, undergraduate, kinetics…

Stopped-flow kinetics techniques are important to the study of rapid chemical and biochemical reactions. Incorporation of a stopped-flow kinetics experiment into the physical chemistry laboratory curriculum would therefore be an instructive addition. However, the usual reactions studied in such exercises employ a corrosive reagent that can over…

In the group exercise described, students are guided through an inductive justification for the spin conservation selection rule ([delta]S = 0). Although the exercise only explicitly involves various states of helium, the conclusion is one of the most widely applicable selection rules for the interaction of light with matter, applying, in various…