Described is research conducted on cluster-assembled matter. The differing character of these arrangements of matter are discussed. Methods used to produce clusters are reviewed. (CW)

Outlined is a method for collecting and cutting oriented samples for microstructural analysis including handling the samples in the laboratory, cutting and orienting chips parallel to the motion plane, and cutting and orienting chips normal to Le and foliation. (CW)

Provides a set of instructions for writing Lewis octet structures which incorporates a simple rule called the "6N+2 Rule." Discusses the importance of these structures in elementary chemistry, biochemistry, and organic chemistry courses. Also discusses non-octet structures and how they are characterized. (JM)

Presented is a technique for making various molecular models from a strip of paper. Instructions for six models including tetrahedral, trigonal bipyramid, octahedral, pentagonal bipyramid, and capped octahedron models are provided. (CW)

Discussed are the mechanisms of nuclear magnetic relaxation, and applications of relaxation times. The measurement of spin-lattice relaxations is reviewed. It is stressed that sophisticated techniques such as these are becoming more important to the working chemist. (CW)

Discussed are the substructures (subgraphs) of imaginary transition structures that provide an effective approach to the characterization of organic reactions. A comparison of conventional methods and this method is presented. (CW)

Describes a set of simple, inexpensive, classical demonstrations of nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) principles that illustrate the resonance condition associated with magnetic dipoles and the dependence of the resonance frequency on environment. (WRM)

This paper reports the results of applying a particular analytical perspective to data from an interview study: a typology of learning impediments informed by research into learning and students' ideas in science. This typology is a heuristic tool that may help diagnose the origins of students' learning difficulties. Here it is applied to data…

Self-assembly or spontaneous assembly is a process in which materials build themselves without assistance. This process plays a central role in the construction of biological structures and materials such as cells, viruses, and bone, and also in abiotic processes like phase transitions and crystal formation. The principles of self-assembly help…

Examined are some of the types of two-dimensional spectra. Their application to nuclear magnetic resonance for the elucidation of molecular structure is discussed. Included are J spectroscopy, H-H correlation spectroscopy, heteronuclear correlation spectroscopy, carbon-carbon correlation, nuclear Overhauser effect correlation, experimental…

Described is an experiment which illustrates valence isomerization, the trapping of a reactive intermediate and retrosynthetic analysis applied to the Diels-Alder reaction. Included is a background discussion, experimental procedures, and a discussion of the analysis. (CW)

The ability to learn and retain novel information depends on a system of structures in the medial temporal lobe (MTL) including the hippocampus and the surrounding entorhinal, perirhinal, and parahippocampal cortices. Damage to these structures produces profound memory deficits; however, the unique contribution to memory of each of these…

Presents coulombic models representing the particles of a system by point charges interacting through Coulomb's law to explain coulombic lattice potential. Uses rubidium manganese trifluoride as an example of cubic perovskite structure. Discusses the effects on cluster properties. (CW)

Compares the similar mathematical problems of molecular vibrational calculations (at any intermediate level of sophistication) and molecular orbital calculations (at the Huckel level). Discusses how the generalizations of Huckel treatment of molecular orbitals apply to vibrational theory. (TW)

Presents the exploded structure method for determination of oxidation states in covalently bound atoms. The three step method is illustrated with four examples and compared to popular textbook presentations. (JM)