Discusses the use of the FT-IR spectrometer in analyses that were previously avoided. Examines some of the applications of this spectroscopy with aqueous solutions, circular internal reflection, samples with low transmission, diffuse reflectance, infrared emission, and the infrared microscope. (TW)

Proposes a simple experiment based on the procedure of Guggenheim and Smith for the determinatin of the dipole moments of two isomeric compounds in nonpolar solvents. Provides background information, laboratory procedures, sample data, results of least squares analysis and discussion of results. (JM)

Describes an undergraduate organic chemistry experiment designed to illustrate the power of nuclear magnetic reasonance spectroscopy in a determination of the configurations at centers of chirality of various isomers of acyclic systems. Provides a background discussion and experimental procedure. (JM)

Briefly describes the application of thermodynamics (system at equilibrium) to the study of the extraction of metals from their oxides (dynamic situation). It is more relevant to study the temperature variation of the equilibrium constants of the reaction than to study the free energy approach. (Author/SK)

Background information, procedures, and typical results are provided for a three-part experiment involving reactions of potassium thiocynate (KNCS) with sulfuric acid. The experiment represents the final stage of structured work prior to students' research projects during their final year. (JM)

Describes how a Polaroid camera can be modified for spectroscopic experiments. Reviews experimental procedures and discusses results that students can obtain within one normal laboratory period. Suggests additional experiments for investigating emission from other sources. (ML)

Two demonstrations are described: (1) a sunset effect using a gooseneck lamp and 20 sheets of paper and (2) the preparation and determination of structural features of dimethyl sulfoxide (DMSO) by infrared spectroscopy. (SK)

Describes an experiment in which stretching a rubber band can be used to compare the statistical theory of rubber elasticity with its continuum mechanics counterpart. Employs the use of the equation of the state of rubber elasticity and the Mooney-Rivlin equation. (TW)

Describes a physical chemistry experiment which uses spectroscopy to measure the heat of formation of Na2SiF6. Discusses the opportunities for students to see the use of a familiar instrument in an unfamiliar application, emphasizing that there are often many ways to attack problems in science. (TW)