A simple bioassay was designed for the detection of adenosine, a human metabolite involved in several physiological processes, on the basis of the functionalization of gold nanoparticles with DNA oligonucleotides selectively binding adenosine. The test was possible thanks to the selective and sensitive binding of adenosine by two DNA…

Reported herein is a multidisciplinary laboratory experiment for advanced undergraduate students that includes elements of material synthesis, in the synthesis of cyclodextrin-containing metal-organic frameworks (CD-MOFs), and environmental chemistry, in the use of these MOFs for pollutant removal. This multiday laboratory experiment starts with…

In this organic chemistry laboratory experiment, students are guided through a series of exercises to understand the behavior of compounds during liquid-liquid extraction. Aspects of density, structure, solubility, acid-base theory, and pK[subscript a] are all incorporated into activities that students complete in groups. After using their initial…

Describes a physical chemistry laboratory experiment that illustrates the concepts of inductive and resonance effects by the calorimetric determination of the heats of protonation of pyridine, 2-chloropyridine, and 3-chloropyridine. (CS)

Describes an experiment that emphasizes the discrete nature of the different oxidation states of vanadium by the separation of ammonium metavanadate into all four species by ion exchange chromatography. (CS)

Crystallization of Magma is one of a series of single-topic problem modules intended for use in undergraduate geology and earth science courses. Through problems and observations based on two sets of experiments, this module leads to an understanding of how an igneous rock can form from molten material. Environmental factors responsible for…

Describes an undergraduate physical chemistry experiment which demonstrates the principles of solution calorimetry and the entropy titration technique. (CS)

Describes a first-year chemistry experiment that illustrates the fundamental concepts of a photoinduced reaction. Qualitative and quantitative parts of the photoreduction of potassium ferrioxalate are detailed. (CS)

Describes an advanced level experiment in which a transition metal cluster compound, cyclopentadienylcarbonyliron tetramer, is synthesized and characterized spectroscopically. Its redox properties are then explored through cyclic voltammetry. (CS)

The different approaches to the generation of power from solar energy may be roughly divided into five categories: distributed collectors; central receivers; biomass; ocean thermal energy conversion; and photovoltaic devices. The first approach (distributed collectors) is the subject of this module. The material presented is designed to…

Describes an electronic technique for making a series of timing measurements in quick succession, using the signal from one photodiode. Two undergraduate experiments, one on linear momentum and the other on angular momentum conservation, are included. (HM)

Describes an experiment which illustrates the general aspects of intermolecular energy transfer between triplet states in rigid solutions of organic compounds solved in an ethanol-ether mixture. Measurements of quenching and energy transfer processes are made using the chemicals of benzophenone and naphthalene. (CS)

Presents a simple, economical model of circulatory behavior that illustrates the effect of changes in cardiac output, peripheral resistance and compliance on arterial blood pressure. (CS)

Provides a list of the reactions commonly used for introductory kinetics studies. These reactions illustrate the kinetics concepts of rate law, rate constant, and reaction order. Describes a kinetic study of the hydrolysis of 3-bromo-3-phenylpropanoic acid which offers many educational advantages. (CS)

A technique is presented for producing holograms using equipment which is already in the possesion of the majority of college physics departments, which includes a slightly modified Michelson interferometer, a helium-neon laser, and a long focal-length lens. Production of high quality holograms has been achieved by inexperienced undergraduates…