Proposes a model for kinetic processes said to be similar in computational effort and yielding similar results to conventional transition state theory (TST), while maintaining parsimony and credulity. Argues that partitioning of states into groups be limited to energy space in contrast to TST. (JM)

Discusses the concept of kinetic versus thermodynamic control of reactions. Explains on the undergraduate level (1) the role of kinetic and thermodynamic control in kinetic equations, (2) the influence of concentration and temperature upon the reaction, and (3) the application of factors one and two to synthetic chemistry. (MVL)

Describes a method of flow injection analysis intended for calculation of complex-formation and redox reaction stoichiometries based on a closed-loop configuration. The technique is suitable for use in undergraduate laboratories. Information is provided for equipment, materials, procedures, and sample results. (JM)

Presented is a method of obtaining accurate rate constants for autocatalytic reactions. The autocatalytic oxidation of dimethylamine by permanganate ion in aqueous solution is used as an example. (RH)

Describes a combination of solutions that can be used in the study of kinetics using the iodine clock reaction. The combination slows down degradation of the prepared solutions and can be used successfully for several weeks. (JRH)

Reviews some important properties of the bimolecular reaction between the hydroxyl radical and carbon monoxide. Investigates the kinetics of the reaction, the temperature and pressure dependence of the rate constant, the state-to-state dynamics of the reaction, and the reverse reaction. (MVL)

Describes a simple redox reaction that occurs between potassium permanganate and oxalic acid that can be used to prepare an interesting disappearing ink for demonstrating kinetics for introductory chemistry. Discusses laboratory procedures and factors that influence disappearance times. (CW)

Describes a Pascal-language based kinetics rate package for the microcomputer. Considers possible ecological uses for the program and illustrates results for several rate laws. Discusses hardware and software needs for adequate operation. (ML)

Describes the scientists and the work they did to study mechanisms of stable complexes of cobalt (III) using kinetic methods. Traces the work from 1946 to the present. (MA)

Presents a parallel treatment of the same phenomena by two approaches (steady-state approximation and approximate solution of the appropriate diffusion equation) to clarify the physical meaning of the important radiation boundary condition in the diffusional derivation. (JN)

Discusses: (1) the Curtin-Hammett (C-H) equation; (2) a direct relationship between product ratio and conformer distribution; (3) the Winstein-Holness (W-H) equation; (4) a combined kinetic treatment using a C-H/W-H utility; and (5) extensions of the C-H/W-H concepts. (JN)

Discusses how, in some circumstances, a two-body reaction (association in absence of a third body) is the only possible association, and how reactions proceed in this case. Taking competition between two/three-body reactions into account, considers relative importance of such combinations and conditions under which the former can be competitive.…

Explains an error that occurs in calculating the conditions for a maximum value of a rate expression for a bimolecular reaction. The rate expression is derived using the Langmuir adsorption isotherm to relate gas pressures and corresponding surface coverages. (GS)

The Langmuir-Hinshelwood equation is fundamental to the study of heterogeneous catalysis, and forms a basis of the study of bimolecular heterogeneous reaction rates. (BB)

Compares the preparation and decomposition of potassium dibromoiodate and of phenyl iodine dichloride in a flexible experiment which accustoms the student to handle halogens, to test for halogens in mixtures, and to appreciate the difference between thermodynamic and kinetic control of reactions. (Author/MA)