Detection of metal ions in solution has been performed without employing H[subscript 2]S or any other sulfide materials. The new method is free from the interference from anions. Identification of Na[superscript +], K[superscript +], and NH[subscript 4][superscript +] has been made possible directly from an aqueous extract of the sample mixture. A…

In this paper, we propose a novel method for deriving Russell-Saunders terms of complex atomic systems with an arbitrary number of equivalent electrons in orbitals with a higher azimuthal number. The method can be regarded as an extension of the classic works of Douglas, McDaniel, and Hyde but with several notable improvements, including the…

The preparation of ethyl acetoacetate is a distinctive, century-old classic organic chemistry laboratory project. Ethyl acetate and sodium metal (sodium ethoxide) are reacted by Claisen ester condensation to produce the sodium salt of ethyl acetoacetate and then obtain the refined product by acidification as well as washing, drying, and…

This paper describes a data set of IR, MS, H-1 NMR, C-13 NMR, DEPT, and 2D NMR spectra designed for undergraduate teaching. The data files are provided as MestReNova documents containing all the available spectra for each of the 251 different compounds in the data set. The spectral data in these files can be processed, manipulated, copied, and…

The essence of higher education is to cultivate innovative talents for the society. Hence, higher education institutions (HEIs), on the one hand, need to respond to social needs and government policies. On the other hand, they need to keep pace with the times and improve the details of teaching to improve the effectiveness of education. In this…

Reactions between metal carbonates from d[superscript 5] to d[superscript 10] systems and glutamic acid are used to obtain molecular metal complexes and metal-organic frameworks (MOFs). When the ligand is an amino acid, these MOFs belong to the BioMOF class (metal-organic frameworks for biological and medical applications). The metal carbonates of…

A chemistry laboratory experiment is described to introduce undergraduate college students to membrane separation technology. This experiment combines a simple nanowire membrane fabrication and visually indicated molecule separation. The membrane is produced via coprecipitation synthesis followed by a filtration assembly process, which can be…

Medicinal chemistry is an integrated discipline that primarily concerns the design, discovery, synthesis, identification, and interpretation of biologically active compounds at the molecular level. To assist undergraduates in understanding the core subjects of medicinal chemistry, we introduced a closed-loop education mode combining fundamentals…

Nitrate is a crucial parameter for assessing water quality, owing to its dual function in ecological systems. These functions can be beneficial or detrimental depending on whether nitrate concentrations are low or high, respectively. The ultraviolet spectrophotometric method (standard as 4500-NO[subscript 3]--B) is a classic method for determining…

A new teaching resource comprised of raw X-ray diffraction data sets from crystallography experiments has been compiled. The aim of this resource is to provide a tool with which to plug the teaching gap between crystals and chemical structures present at various levels of education, as well as providing examples for early stage researchers and…

In a General, Organic, and Biological (GOB) Chemistry course designed for allied-health disciplines, new information builds on previous material. It is important for students to retain what they learn throughout the course and be able to integrate the material not only with material from other bioscience courses but also with the metabolism…

Energy conversion devices such as fuel cells, metal-air batteries, and electrolyzers have been envisaged as possible solutions for cutting down the continuous accumulation of greenhouse gases resulting from the combustion of fossil fuel. The bottleneck reaction for these devices is the oxygen reduction reaction (ORR) occurring at the cathode. The…

Teaching graduate students the entanglements of the interdisciplinary field of electrochemical DNA biosensors in microfluidics can be challenging, as it involves multiple fields of research strongly interacting with each other. Yet, electrochemical biosensors coupled with the improved hydrodynamics of microfluidics allow for simpler, more…

We have revamped a classic analytical chemistry laboratory experiment, "Determination of an Unknown Acid", to provide students an opportunity to learn about new advances in the material sciences and their applications in analytical chemistry in an effort to reinforce the key concepts of chemical analysis. Specifically, students were…

A simple method to determine Lewis electron dot structures and formal charges without a need to sum all of the valence electrons, reorganize electron pairs, draw and pair up individual electrons, or remember a formal charge formula is described. The formal charge is determined by the group number (number of valence electrons) and the number of…