Presents entropy analysis of four processes: a chemical reaction, a heat engine, the dissolution of a solid, and osmosis. Discusses entropy, the second law of thermodynamics, and the Gibbs free energy function. (MVL)

Discusses the importance of ion chromatography in separating and measuring anions. The principles of ion exchange are presented, along with some applications of ion chromatography in industry. Ion chromatography systems are described, as well as ion pair and ion exclusion chromatography, column packings, detectors, and programming. (TW)

Discusses ways that chemists have traditionally used models to represent chemical structures. Suggests new ways to construct three-dimensional models of receptor sites using thermoplastics or heavy aluminum foil. Provides sketches and photographs of several models. Points out the advantages of using such models over traditional two-dimensional…

Reviews the historical development of the periodic table, examining major changes due to understanding of radioactivity, synthetic transmutation by bombardment, differences between transuranium elements and the lanthanide series, and the transactinide elements. Discusses the continuing work on atomic synthesis and its importance in extending our…

Outlines a multidisciplinary course which comprises fundamental, practical, and experimental aspects of heterogeneous catalysis. The course structure is a combination of lectures and demonstrations dealing with the use of spectroscopic techniques for surface analysis. (SK)

Describes several experiments using the techniques of thermal analysis and thermometric titrimetry. Defines thermal analysis and several recent branches of the technique. Notes most of the experiments use simple equipment and standard laboratory techniques. (MVL)

Discusses a new method for determining the eigenvalues of the Schroedinger equation when the potential energy function does not have a simple form. Describes the mathematical methods and provides an application. Lists limitations to the method. (MVL)

Questions the use of the Reactivity Selectivity Principle (RSP) by teachers and authors of texts in discussing organic reaction mechanisms. Provides some applications and failures of the use of the RSP, reviews some quantitative aspects of the RSP, and discusses some of the rationalization of the RSP failures. (TW)

Explores the applicability of Mulliken's united atom model to a variety of chemical systems and demonstrates its value as a teaching tool. Considers applications to first row hydrides, compounds of the first and second periods, heavy atoms, and cluster systems. (MVL)

Investigates the four week chemistry program in a summer program in science and mathematics. Identifies weekly topics for the program: (1) color and visible spectroscopy; (2) UV spectroscopy, fluorescence, and chemiluminescence; (3) IR and NMR spectroscopy; and (4) lists 12 individual projects. (MVL)

Addresses the requirements of high school students and noncrystallographers in lectures on crystals, diffraction, and structure analysis. Discusses basic understanding and a sequence that addresses these requirements. Suggests visual and descriptive teaching methods used in this effort. (CW)

Discusses the composition and properties of various types of coal. Follows the origin of coal and amounts available in the ground. Explores the anaerobic decay needed to produce coal. Touches upon the greenhouse effect. (MVL)

Uses simple pulse NMR experiments to discuss Fourier transforms. Studies the generation of spin echoes used in the imaging procedure. Shows that pulse NMR experiments give signals that are additions of sinusoids of differing amplitudes, frequencies, and phases. (MVL)

Investigates ground state electron configurations for some common elements using graphical methods. Bases observed tendencies on following ideas: "occupancy of differing shells, occupancy of differing subshells within a given shell, double occupancy vs. single occupancy of an orbital, and quantum-mechanical exchange." (ML)

Describes a procedure for constructing point groups based on the symmetric parent molecules of methane and adamantane. Intended for use in teaching concepts such as subgroups and cosets to beginners in group theory. (TW)