Electrochemical characterization techniques are essential for studying and developing advanced materials across various fields, from corrosion science to energy storage, photovoltaics, and bioelectrochemistry. However, these techniques are often under-represented in educational curricula. This practical guide with a hands-on laboratory experiment…

Electrophilic aromatic substitution (S[subscript E]Ar) and nucleophilic aromatic substitution (S[subscript N]Ar) reactions are among the most valuable reactions in the conversion of aromatic rings. While these reactions are typically covered in separate experiments in undergraduate organic courses, a continuous experimental setup elucidating both…

A laboratory experiment that involves the aqueous and solid phase synthesis, characterization, and solvatochromic properties exploration of red complex [Ni(Me[subscript 3]en)(acac)]BPh[subscript 4] has been developed for first-year undergraduates in the College of Chemistry and Chemical Engineering at Xiamen University. In contrast to previously…

Four General Chemistry instructors investigated the use of ChatGPT-4 to improve their lessons plans for the historical experiments of Thomson, Millikan, and Rutherford. The instructors varied in their prior knowledge for these experiments and their initial lessons addressed somewhat different learning objectives. This led to different…

Photochemical reactions are initiated by the absorption of light, triggering the chemical reactions and resulting in the formation of products. These reactions are generally performed using a freely available renewable source of energy-solar energy. Solar simulators mimic both the ultraviolet and visible regions of sunlight and hence can serve as…

The discovery of ferrocene, Fe(C[subscript 5]H[subscript 5])[subscript 2], in the 1950s sparked the development of organometallic chemistry including metallocene compounds. Shortly after the isolation of ferrocene, the analogous ruthenium and osmium compounds were discovered. The preparation of ferrocene is common in undergraduate inorganic…

Previous educational articles on microfluidic technology mainly focused on continuous microfluidics, so we set up an undergraduate laboratory experiment to introduce droplet microfluidics to students. Students can understand the concept of microfluidic channels and the principles of droplet microfluidics, prepare polydimethylsiloxane (PDMS)…

The addition of a small excess of triethyl orthoformate to an alcoholic mixture of NiCl[subscript 2]·6H[subscript 2]O and triphenylphosphine (PPh[subscript 3]) results in an increase in the typical isolated yield of [NiCl[subscript 2](PPh[subscript 3])[subscript 2]] from below 50% to over 85%. The impact of water when present in the reaction…

The formation of chemical patterns is in general difficult to control due to the random diffusive motions of the reacting chemical species in solution. In this paper, we present a new method using audible sound to control the formation of chemical patterns obtained in blue bottle experiments. The waves generated on the surface of the solution by…

Electrochemistry represents a powerful sustainable method for chemical synthesis; however, its widespread application is limited due to the lack of exposure and appropriate basic training of synthetic chemists and engineers in electrochemistry and electrochemical engineering. The introduction of diverse laboratory practices to the current…

We investigated a very long chain falling from the pile on the edge of a table to the floor both experimentally and theoretically. In this very simple and novel configuration we showed that the velocity of the chain quickly converges to its asymptotic value, and that the steady-state velocity is proportional to the square root of the height of the…

The measurement of the charge-to-mass ratio, e/m, of the electron is a fundamental part of any study of electricity and magnetism. It is possible to use an apparatus designed to measure e/m for other things, including investigations of electron flow through a near vacuum, measuring a work function, and even exploring some quantum mechanics…

Our first experience of dimension typically comes in the intuitive Euclidean sense: a line is one dimensional, a plane is two dimensional, and a volume is three dimensional. However, following the work of Mandelbrot, systems with a fractional dimension, "fractals," now play an important role in science. The novelty of encountering…

Students determine the iron mass in dietary supplements using four colorimetric assays. These colorimetric assays were selective for Fe[superscript 3+]. It was complexed by thiocyanide, salicylate, gallic acid, and Fe(CN)[subscript 6][superscript 4-], forming blood-red, red, violet, and blue complexes, respectively. The [lambda][subscript max] of…

Applying the idea of green chemistry, we extended an esterification teaching experiment with isoamyl alcohol and acetic acid and reused isoamyl acetate in the transesterification reaction with KOH as the catalyst. As a result, isoamyl alcohol was produced and could be reused for the teaching experiment. The simplified experimental method achieved…