Theoretical yield and extent of reaction (degree of completion) are important concepts in stoichiometry and in chemical kinetics. We provide expressions describing theoretical yield (Y) and maximum extent of reaction (fractional yield, f[subscript max]) for five examples of commonly encountered reversible chemical reactions: A [equilibrium sign]…

The problem of a disc or cylinder initially rolling with slipping on a surface and subsequently transitioning to rolling without slipping is often cited in textbooks. Students struggle to qualitatively understand the difference between kinetic and static frictional forces--i.e., whereas the magnitude of the former is known, that of the latter can…

The pharmaceutical and medicine manufacturing industry has become the largest industrial sector for the employment of chemists, indicating a need for experiments with a pharmaceutical sciences context in the undergraduate chemistry curriculum. In the pharmaceutical industry, testing drug dissolution is a key analytical task for solid oral dosage…

Understanding the physicochemical properties of organic compounds with potential biological uses is central in current research topics. Thus, students must pursue the integration of different fields of chemistry to obtain and understand the physicochemical parameters that characterize the mechanism of action of key organics compounds. This…

Alpha-particle sources are widely used in industrial and medical applications. Such applications include smoke detectors, static charge eliminators, and radiation therapy. This paper is concerned with the detection of alpha particles. A number of techniques are known for the detection of alpha particles. Those techniques include the Geiger-Müller…

Nonlinear chemical reactions produce interesting chemohydrodynamic patterns in an unstirred medium, which act as interesting demonstrations to display the novel phenomena in a nonequilibrium chemical system. Here, we report new outreach experiments: pH chemohydrodynamic patterns modulated by sodium polyacrylate in the bromate-sulfite-ferrocyanide…

The basic SIR (susceptible-infectious-removed) model of epidemiology is presented in chemical kinetic terms with a simple two-reaction mechanism. The conditions for the development of epidemics, the course of a simple closed epidemic, and the bases of several mitigation strategies are described in terms of the underlying first- and second-order…

The inhibition of porcine pancreatic lipase by the drug orlistat was studied through a series of activities that combine experimental and computational procedures. The enzymatic activity of the lipase was determined by measuring enzyme kinetics and calculating parameters such as K[subscript m] and V[subscript max] from experimental data. Assays of…

A simple photometric device was built to measure the kinetics of the title reaction. The device consisted of a green light-emitting diode (centered at 520 nm), a sample vial, a photodiode, and an Arduino microcontroller board. These parts were mounted on a black poly(lactic acid) holder which was manufactured by utilizing three-dimensional…

This paper describes the creation of a theme-based first quarter, of a two quarter sequence, general chemistry laboratory course following an argument driven inquiry format and employing specifications grading. The course contains four, two-week projects investigating the chemistry of a popular sports drink. The sugar content, dye concentration,…

Enzymes provide attractive targets for drug development. Quantitative analysis of enzyme reactions can lead to rational drug discovery. For undergraduates majoring in biochemistry or pharmacy and engaged in drug discovery-related work, it is essential to acquire a comprehensive understanding of enzyme kinetics, including experimental methods and…

An integrated system comprising a commercial high-performance liquid chromatography HPLC (except autosampler) equipped with an external multichannel autofeeding module was developed to accomplish interference-free separation and kinetic tracking for the H[subscript 2]O[subscript 2]-thiourea reaction, which is proposed as a lab experiment for…

The distinction between pressure in a liquid and in a gas is often treated in a cursory way, or not treated at all, even in university level textbooks. Most texts fail to point out the relation between pressure and density in a gas as compared to pressure in a--virtually incompressible--liquid. In many instances this also results in a dismissive…

The field of biosensors is a burgeoning area of research and employs a large number of chemistry graduates. The impact of strip tests in detecting coronavirus was palpable during the recent COVID-19 pandemic and will further drive the biosensor industry. Despite their common usage, a coherent introduction to the basics of sensing remains missing…

The Hill equation, which models the cooperative ligand-receptor binding equilibrium, turns out to be useful in modeling the progression of infectious disease outbreaks such as CoViD-19. The equation fits well the data for total and daily case numbers, allows tentative predictions for the half-point and end point of the epidemic, and presents a…