Stereoselective reduction of ketones to alcohols using baker's yeast is a classic experiment in the undergraduate laboratory. Here we illustrate the reduction of racemic ethyl 2-fluoro-3-oxobutanoate to the corresponding alcohol using a set of four commercially available ketoreductases (KREDs). The reaction sets two stereocenters with four…

This study reports an undergraduate laboratory experiment that explores the temperature-dependent kinetics of caffeine release during tea steeping by using quantitative [superscript 1]H NMR spectroscopy with a water suppression pulse sequence. Designed for introductory organic chemistry laboratory courses, the experiment emphasizes the real-world…

Chemical kinetics is a branch of physical chemistry that constitutes an essential part of undergraduate education. In general, a complex and expensive experimental apparatus is indispensable for observing the kinetics of a chemical process owing to the continuity of chemical reactions. Thus, intuitive visualization of the chemical kinetics using a…

Nonlinear chemical reactions produce interesting chemohydrodynamic patterns in an unstirred medium, which act as interesting demonstrations to display the novel phenomena in a nonequilibrium chemical system. Here, we report new outreach experiments: pH chemohydrodynamic patterns modulated by sodium polyacrylate in the bromate-sulfite-ferrocyanide…

A laboratory experiment that exposes students to fundamental concepts in kinetics and statistical thermodynamics to study systems of great current interest in nanotechnology by employing a foundational technique in physical chemistry is described. A modified commercial flash photolysis spectrometer was used to study photoinduced isomerization…

A laboratory experiment is described in which students carry out immobilization of the enzyme invertase via entrapment in alginate (Ca-alginate) and, accordingly, estimate values for kinetic constants and mass transfer coefficients. Immobilization of enzymes, or confinement thereof to a defined space with retention of most catalytic activity, is…

The principles of chemical kinetics comprise one of the core topics that appear throughout chemistry. Standard kinetics lessons typically cover reaction rates and relative rates, rate laws, integrated rate laws, half-lives, collision theory, and the Arrhenius equation. They can also introduce a discussion of mechanisms as well, which may be the…

A central theme in introductory and advanced chemical education courses pertains directly to the transfer of electrons between atoms, ions, or molecules. This article presents theoretical treatments of electron transfer with specific attention toward applying these principles to experiment. The goal is to revitalize teaching electron transfer at…

Herein we present an engaging description of the existent analogy between social distancing during the COVID-19 pandemic and the collision cross-section of particles as defined in the collisional model for a chemical reaction. In addition, the link between collision cross-sections and kinetic rate constants is thoroughly established, bridging…

An introduction to digital stochastic simulations for modeling a variety of physical and chemical processes is presented. Despite the importance of stochastic simulations in chemistry, the prevalence of turn-key software solutions can impose a layer of abstraction between the user and the underlying approach obscuring the methodology being…

Herein, we present an experience-based learning approach that uses the COVID-19 pandemics knowledge about virus spread and epidemics to establish an analogy between a simple epidemics model--the SIR model (susceptible--infected--removed), and a second-order autocatalytic reaction with subsequent catalyst deactivation. Our approach provides a…

Here we present a new undergraduate laboratory that will introduce the concepts of time-resolved spectroscopy and provide insight into the natural time scales on which chemical dynamics occur through direct measurement. A quantitative treatment of the acquired data will provide a deeper understanding of the role of quantum mechanics and various…

A Unit Operations Laboratory (UOL) is fundamental to undergraduate chemical engineering education. This article discusses a new course structure for the University of Kansas UOL and details for three new experiments covering the fundamentals of vapor-liquid equilibrium, fluid mechanics, and kinetics. Students apply knowledge from these courses as…

KinSim is a research-grade, interactive, user-friendly, open-source, and visual software for kinetics modeling of environmental chemistry and other applications. Students without any computer-programming background and limited knowledge of environmental chemistry can use KinSim, which also includes multiple features and functionality dedicated to…

The term "the practice of physical activity" was recently introduced as one of the four elements of the American Kinesiology Association undergraduate core curriculum. The purpose of this article is to articulate the nature of the term by offering a philosophical justification (other than health) for including physical activity…