Ion transport, involving the diffusion and migration of ions within the electrolyte, stands as a fundamental concept in electrochemistry and serves as the driving force for electrochemical reactions. Electric double layers are critical in the fields of electrochemical energy storage and chemical conversion, constituting a central focus of…

Benzoin, an [alpha]-hydroxy ketone, is stereoselectively reduced by sodium borohydride to yield hydrobenzoin, the stereochemistry of which is determined by acetalization and analysis of the derivative by NMR spectroscopy. This classical experiment has been enhanced by modern spectroscopic and computational analysis to enable students to…

A simple experiment is described to compare the descent time between two vertically separated points when an object slides down tracks of varying shape. A surprising result is that the descent time is shortest when it follows a circular track rather than a cycloidal track. Cycloidal tracks are usually predicted to result in the shortest descent…

Calculating analytical uncertainties as a part of method validation is a relevant aspect of field and laboratory practices in instrumental analytical chemistry subjects, which usually require complex algorithms. This work describes the development and didactic use of an automatic and straightforward informatics tool, implemented in an Excel macro,…

As simple and ubiquitous redox-active organic molecules, quinones participate in diverse electron transfer processes in chemistry and biological systems for energy transformation and signal transduction. We introduce here a practical exercise to study the redox potentials of benzoquinone and its two derivatives by combining the electrochemistry…

A computational experiment investigating common organic chemistry mechanisms has been developed and implemented in a junior/senior-level physical chemistry laboratory course at two institutions. Students investigated various reactions that proceed via S[subscript N]1, S[subscript N]2, E1, and E2 mechanisms using hybrid Density Functional Theory…

Calculating the duration of a motion when the applied net force on the moving body changes with time is usually a challenging task. In most cases, the only example of the duration of a motion when the acceleration is not constant presented to introductory physics students worldwide is the example of harmonic motion. A discussion with respect to…

A well known physics problem is to calculate the friction forces required to support a ladder against a wall. A more tractable problem is to calculate the friction forces needed to support an inclined beam on a ball or a cylinder. In the latter case there are three rather than two points of sliding support. Measurements and calculations are…

Science and engineering students in the second semester of a calculus-based physics sequence typically study and measure the on-axis magnetic field for a multiple, circular turn coil. There are four benefits to this approach: 1) an analytical solution is easily obtained, 2) the coil is easily constructed using tightly wound, high-gauge wire where…

A solid ball placed on a rotating turntable is known to roll slowly around a circular path, at a speed 3.5 times slower than the turnable itself. If the ball is located in a straight track across a diameter of the turntable, then it accelerates rapidly to the edge. Both effects were filmed in slow motion using a video camera and a cake decoration…

We discuss the limits of the equation of the period of a simple pendulum, T[subscript s] = 2[pi][square root]l/g, frequently used in high-school and university classrooms to measure the acceleration of gravity. We evaluate the relative error in determining the acceleration of gravity with this simple equation instead of a more realistic one,…

Interaction forces between magnetic fields and current loops play a central role in the theory of magnetism. This work describes a reasonably simple and cheap experiment for demonstrating this issue: the force on a thin coil due to a nearby cylindrical magnet. The magnitude of the force as well as its attractive/repulsive character is comfortably…

In a paper (posthumously) co-authored by Isaac Newton himself, the primacy of geometric notions in pedagogical expositions of centripetal acceleration has been clearly asserted. In the present paper we demonstrate how this pedagogical prerogative can inform the design of an experiment involving an accelerometer-equipped smartphone rotating…

This paper develops the ideas of "The Pedagogical Power of Context: Iterative Calculus Methods and the Epidemiology of Eyam" (French "et al." 2018 "J. Phys. Educ."), where we considered the application of the Euler method to solve epidemiological problems. Our purpose was to convey some examples of school level work…

A series of computational laboratory experiments aimed at teaching students principles of rational drug design are described and evaluated. These experiments range from an introduction to viewing protein-ligand complexes to optimizing geometries of potential drugs with quantum chemistry and automated docking. Student feedback indicates that such a…