Ion transport, involving the diffusion and migration of ions within the electrolyte, stands as a fundamental concept in electrochemistry and serves as the driving force for electrochemical reactions. Electric double layers are critical in the fields of electrochemical energy storage and chemical conversion, constituting a central focus of…

Calculating analytical uncertainties as a part of method validation is a relevant aspect of field and laboratory practices in instrumental analytical chemistry subjects, which usually require complex algorithms. This work describes the development and didactic use of an automatic and straightforward informatics tool, implemented in an Excel macro,…

As simple and ubiquitous redox-active organic molecules, quinones participate in diverse electron transfer processes in chemistry and biological systems for energy transformation and signal transduction. We introduce here a practical exercise to study the redox potentials of benzoquinone and its two derivatives by combining the electrochemistry…

A computational experiment investigating common organic chemistry mechanisms has been developed and implemented in a junior/senior-level physical chemistry laboratory course at two institutions. Students investigated various reactions that proceed via S[subscript N]1, S[subscript N]2, E1, and E2 mechanisms using hybrid Density Functional Theory…

One of the main topics of elementary physics is the idea that every material is composed of "little particles that move around in perpetual motion, attracting each other when they are a little distance apart, but repelling upon being squeezed into one other." These particles could be atoms or molecules. Atoms are the smallest part into…

Design-Based Learning and computational thinking (CT) are two key components that support each other specifically in the learning process involving the development of experimental design. Both components emphasize the importance of integration between computational thinking and design-based learning to support a creative, innovative and data…

We discuss the limits of the equation of the period of a simple pendulum, T[subscript s] = 2[pi][square root]l/g, frequently used in high-school and university classrooms to measure the acceleration of gravity. We evaluate the relative error in determining the acceleration of gravity with this simple equation instead of a more realistic one,…

An undergraduate-level Computational Chemistry project was incorporated initially into a Physical Chemistry course and then into the laboratory curriculum in the subsequent application. Before the introduction of the project, the lectures covered quantum chemistry, spectroscopy, and kinetics while simultaneously including computational chemistry…

In general, undergraduate experimental physics laboratories do not usually have experiments designed to address rolling friction and to measure the value of the rolling friction coefficient. This work explores an experiment, which has the potential to arouse students' curiosity about rolling friction by addressing a counterintuitive aspect of the…

A series of computational laboratory experiments aimed at teaching students principles of rational drug design are described and evaluated. These experiments range from an introduction to viewing protein-ligand complexes to optimizing geometries of potential drugs with quantum chemistry and automated docking. Student feedback indicates that such a…

A computational laboratory experiment investigating molecular models for hexagonal boron-carbon-nitrogen sheets (h-BCN) was developed and employed in an upper-level undergraduate chemistry course. Students used the Avogadro user interface for molecular editing and the WebMO interface for the quantum computational workflow. Density functional…

Surface modification has been considered as a fundamental item in upper-division undergraduate and master courses. Thus, the development of experiments regarding processes and characterization of surface-modification phenomena is highly desired. In this article, we propose an electrochemical and computational study of widely used…

The effects of substitution on reaction rates are at the heart of both physical chemistry and organic chemistry. In this paper, we present a computational laboratory module to explore the effects of group substitution and isotopic substitution on reaction rates by using a readily accessible graphical interface, a computational engine, and…

In the field of physics teaching, the simple pendulum provides a very simple way to study the harmonic oscillator, the source of some fundamental concepts such as periodicity, relaxation time and anharmonicity. As such, its experimental study is frequently integrated into high school or first year university programs. With this in mind, in this…

Providing exposure to the process and methods of science is a fundamental goal of any general education college science course. This is largely because most students taking such courses are generally "not" science majors, so they are likely to take few, if any, other science courses. Meeting this goal can be a challenge in courses such…